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1

The Impact of Palladium(II) Reduction Pathways on the Structure and Activity of Palladium(0) Catalysts

Wei, Carolyn S., Davies, Geraint H. M., Soltani, Omid, Albrecht, Jacob, Gao, Qi, Pathirana, Charles, Hsiao, Yi, Tummala, Srinivas, Eastgate, Martin D.

Journal:

Angewandte Chemie International Edition

Year:

2013

Language:

english

File:

PDF, 717 KB

english, 2013

2

Nickel-Catalyzed Barton Decarboxylation and Giese Reactions: A Practical Take on Classic Transforms

Qin, Tian, Malins, Lara R., Edwards, Jacob T., Merchant, Rohan R., Novak, Alexander J. E., Zhong, Jacob Z., Mills, Riley B., Yan, Ming, Yuan, Changxia, Eastgate, Martin D., Baran, Phil S.

Journal:

Angewandte Chemie International Edition

Year:

2017

Language:

english

File:

PDF, 2.56 MB

english, 2017

3

Leveraging a “Catch-Release” Logic Gate Process for the Synthesis and Non-Chromatographic Purification of Thioether or Amine Bridged Macrocyclic Peptides

Kheirabadi, Mahboubeh, Creech, Gardner S., Qiao, Jennifer X, Nirschl, David S., Leahy, David K., Boy, Kenneth M., Carter, Percy H, Eastgate, Martin D.

Journal:

Journal of Organic Chemistry

Year:

2018

Language:

english

File:

PDF, 631 KB

english, 2018

4

Palau’chlor: A Practical and Reactive Chlorinating Reagent

Rodriguez, Rodrigo A., Pan, Chung-Mao, Yabe, Yuki, Kawamata, Yu, Eastgate, Martin D., Baran, Phil S.

Journal:

Journal of the American Chemical Society

Year:

2014

Language:

english

File:

PDF, 1.64 MB

english, 2014

5

Development of a Robust Process for the Preparation of High-Quality Dicyclopropylamine Hydrochloride

Mudryk, Boguslaw, Zheng, Bin, Chen, Ke, Eastgate, Martin D.

Journal:

Organic Process Research & Development

Year:

2014

Language:

english

File:

PDF, 762 KB

english, 2014

6

Scalable and sustainable electrochemical allylic C–H oxidation

Horn, Evan J., Rosen, Brandon R., Chen, Yong, Tang, Jiaze, Chen, Ke, Eastgate, Martin D., Baran, Phil S.

Journal:

Year:

2016

Language:

english

File:

PDF, 1.67 MB

english, 2016

7

Development of a Safe and Robust Process for the Large-Scale Preparation of a Vinyl Bromide from a Ketone Using a (PhO) 3 P/Br 2 -Derived Reagent

Likhite, Nachiket, Ramasamy, Sivaraj, Tendulkar, Shankar, Sathasivam, Shunmugaraj, Luzung, Michael, Zhu, Ye, Strotman, Neil, Nye, Jeffrey, Ortiz, Adrian, Kiau, Susanne, Eastgate, Martin D., Vaidyanath

Journal:

Organic Process Research & Development

Year:

2016

Language:

english

File:

PDF, 1.12 MB

english, 2016

8

Ligand-Promoted Meta-C–H Arylation of Anilines, Phenols, and Heterocycles

Wang, Peng, Farmer, Marcus E., Huo, Xing, Jain, Pankaj, Shen, Peng-Xiang, Ishoey, Mette, Bradner, James E., Wisniewski, Steven R., Eastgate, Martin D., Yu, Jin-Quan

Journal:

Journal of the American Chemical Society

Year:

2016

Language:

english

File:

PDF, 1.90 MB

english, 2016

9

Decarboxylative Peptide Macrocyclization through Photoredox Catalysis

McCarver, Stefan J., Qiao, Jennifer X., Carpenter, Joseph, Borzilleri, Robert M., Poss, Michael A., Eastgate, Martin D., Miller, Michael, MacMillan, David W. C.

Journal:

Angewandte Chemie International Edition

Year:

2016

Language:

english

File:

PDF, 1.90 MB

english, 2016

10

On the design of complex drug candidate syntheses in the pharmaceutical industry

Eastgate, Martin D., Schmidt, Michael A., Fandrick, Keith R.

Journal:

Nature Reviews Chemistry

Year:

2017

Language:

english

File:

PDF, 615 KB

english, 2017

11

Development of Robust, Scaleable Catalytic Processes through Fundamental Understanding of Reaction Mechanisms

Wei, Carolyn S., Simmons, Eric M., Hsaio, Yi, Eastgate, Martin D.

Journal:

Topics in Catalysis

Year:

2017

Language:

english

File:

PDF, 1.40 MB

english, 2017

12

Ni(COD)(DQ): An Air-Stable 18-Electron Ni(0)-Olefin Precatalyst

Tran, Van, Li, Zi-Qi, Apolinar, Omar, Derosa, Joseph, Wisniewski, Steven, Joannou, Matthew V., Eastgate, Martin, Engle, Keary Mark

Journal:

Angewandte Chemie International Edition

Year:

2020

File:

PDF, 1.51 MB

2020

13

Mechanistic Insight into the Palladium-Catalyzed 1,4-Oxidation of 1,3-Dienes to 1,4-Dicarboxy-alk-2-enes

Martin D. Eastgate, Frederic G. Buono

Journal:

Angewandte Chemie

Year:

2009

Language:

english

File:

PDF, 474 KB

english, 2009

14

Mechanistic Insight into the Palladium-Catalyzed 1,4-Oxidation of 1,3-Dienes to 1,4-Dicarboxy-alk-2-enes

Martin D. Eastgate, Frederic G. Buono

Journal:

Angewandte Chemie International Edition

Year:

2009

Language:

english

File:

PDF, 474 KB

english, 2009

15

ChemInform Abstract: Chemistry of Lithiated Phosphine Oxides: Stereoselective Synthesis of Alkene-4,5-diols.

Thomas Boesen, Neil Feeder, Martin D. Eastgate, David J. Fox, Jonathan A. Medlock, Charles R. Tyzack, Stuart Warren

Journal:

Year:

2001

Language:

english

File:

PDF, 40 KB

english, 2001

16

Sulfur-Mediated Ritter Reactions: The Synthesis of Cyclic Amides.

Martin D. Eastgate, David J. Fox, Thomas J. Morley, Stuart Warren

Journal:

Year:

2003

File:

PDF, 161 KB

2003

17

Lewis Base Activation of Lewis Acids: Catalytic, Enantioselective Addition of Silyl Ketene Acetals to Aldehydes.

Scott E. Denmark, Gregory L. Beutner, Thomas Wynn, Martin D. Eastgate

Journal:

Year:

2005

File:

PDF, 48 KB

2005

18

Lewis Base Catalyzed, Enantioselective Aldol Addition of Methyl Trichlorosilyl Ketene Acetal to Ketones.

Scott E. Denmark, Yu Fan, Martin D. Eastgate

Journal:

Year:

2005

File:

PDF, 40 KB

2005

19

Regioselective synthesis of 1,4-disubstituted imidazoles

Schmidt, Michael A., Eastgate, Martin D.

Journal:

Organic & Biomolecular Chemistry

Year:

2012

Language:

english

File:

PDF, 306 KB

english, 2012

20

ChemInform Abstract: Regioselective Synthesis of 1,4-Disubstituted Imidazoles.

Michael A. Schmidt, Martin D. Eastgate

Journal:

Year:

2012

File:

PDF, 32 KB

2012

21

Development of a Process for the Preparation of Chloromethyl Chlorosulfate

Zheng, Bin, Sugiyama, Masano, Eastgate, Martin D., Fritz, Alan, Murugesan, Saravanababu, Conlon, David A.

Journal:

Organic Process Research & Development

Year:

2012

Language:

english

File:

PDF, 365 KB

english, 2012

22

The Development of Scalable and Efficient Methods for the Preparation of Dicyclopropylamine HCl Salt

Chen, Ke, Eastgate, Martin D., Zheng, Bin, Li, Jun

Journal:

Organic Process Research & Development

Year:

2011

Language:

english

File:

PDF, 912 KB

english, 2011

23

Synthesis of Enantiomerically Pure 2,2,3,4,5-Pentasubstituted Pyrrolidines by Phenylsulfanyl Migration †

Baldwin, I. Craig, Briner, Paul, Eastgate, Martin D., Fox, David J., Warren, Stuart

Journal:

Organic Letters

Year:

2002

Language:

english

File:

PDF, 109 KB

english, 2002

24

Regioselective Bromination of Fused Heterocyclic N -Oxides

Wengryniuk, Sarah E., Weickgenannt, Andreas, Reiher, Christopher, Strotman, Neil A., Chen, Ke, Eastgate, Martin D., Baran, Phil S.

Journal:

Organic Letters

Year:

2013

Language:

english

File:

PDF, 472 KB

english, 2013

25

The chemistry of lithiated phosphine oxides: the stereoselective synthesis of alkene-4,5-diols

Boesen, Thomas, Feeder, Neil, Eastgate, Martin D., Fox, David J., Medlock, Jonathan A., Tyzack, Charles R., Warren, Stuart

Journal:

Journal of the Chemical Society Perkin Transactions 1

Year:

2001

Language:

english

File:

PDF, 489 KB

english, 2001

26

Lewis Base Activation of Lewis Acids: Catalytic, Enantioselective Addition of Silyl Ketene Acetals to Aldehydes

Denmark, Scott E., Beutner, Gregory L., Wynn, Thomas, Eastgate, Martin D.

Journal:

Journal of the American Chemical Society

Year:

2005

Language:

english

File:

PDF, 297 KB

english, 2005

27

ChemInform Abstract: Regioselective Bromination of Fused Heterocyclic N-Oxides.

Wengryniuk, Sarah E., Weickgenannt, Andreas, Reiher, Christopher, Strotman, Neil A., Chen, Ke, Eastgate, Martin D., Baran, Phil S.

Journal:

Year:

2013

File:

PDF, 40 KB

2013

28

A Mild, Ferrocene-Catalyzed C–H Imidation of (Hetero)Arenes

Foo, Klement, Sella, Eran, Thomé, Isabelle, Eastgate, Martin D., Baran, Phil S.

Journal:

Journal of the American Chemical Society

Year:

2014

Language:

english

File:

PDF, 2.04 MB

english, 2014

29

On the Mechanism of Lewis Base Catalyzed Aldol Addition Reactions: Kinetic and Spectroscopic Investigations Using Rapid-Injection NMR

Denmark, Scott E., Eklov, Brian M., Yao, Peter J., Eastgate, Martin D.

Journal:

Journal of the American Chemical Society

Year:

2009

Language:

english

File:

PDF, 3.39 MB

english, 2009

30

Lewis Base Catalyzed, Enantioselective Aldol Addition of Methyl Trichlorosilyl Ketene Acetal to Ketones

Denmark, Scott E., Fan, Yu, Eastgate, Martin D.

Journal:

Journal of Organic Chemistry

Year:

2005

Language:

english

File:

PDF, 462 KB

english, 2005

31

A Method for Heteroaromatic Nitration Demonstrating Remarkable Thermal Stability

Beutner, Gregory L., Desai, Lopa, Fanfair, Dayne, Lobben, Paul, Anderson, Eric, Leung, Simon W., Eastgate, Martin D.

Journal:

Organic Process Research & Development

Year:

2014

Language:

english

File:

PDF, 1.11 MB

english, 2014

32

ChemInform Abstract: A Mild, Ferrocene-Catalyzed C-H Imidation of (Hetero)Arenes.

Foo, Klement, Sella, Eran, Thome, Isabelle, Eastgate, Martin D., Baran, Phil S.

Journal:

Year:

2014

File:

PDF, 22 KB

2014

33

Ligand-Promoted ortho -CH Amination with Pd Catalysts

Zhu, Dajian, Yang, Guoqiang, He, Jian, Chu, Ling, Chen, Gang, Gong, Wei, Chen, Ke, Eastgate, Martin D., Yu, Jin-Quan

Journal:

Angewandte Chemie International Edition

Year:

2015

Language:

english

File:

PDF, 645 KB

english, 2015

34

Mechanistic Insights into the Vanadium-Catalyzed Achmatowicz Rearrangement of Furfurol

Ji, Yining, Benkovics, Tamas, Beutner, Gregory L., Sfouggatakis, Chris, Eastgate, Martin D., Blackmond, Donna G.

Journal:

Journal of Organic Chemistry

Year:

2015

Language:

english

File:

PDF, 1.72 MB

english, 2015

35

Development of a Diastereoselective Phosphorylation of a Complex Nucleoside via Dynamic Kinetic Resolution

Tran, Kristy, Beutner, Gregory L., Schmidt, Michael, Janey, Jacob, Chen, Ke, Rosso, Victor, Eastgate, Martin D.

Journal:

Journal of Organic Chemistry

Year:

2015

Language:

english

File:

PDF, 735 KB

english, 2015

36

Current complexity: a tool for assessing the complexity of organic molecules

Li, Jun, Eastgate, Martin D.

Journal:

Organic & Biomolecular Chemistry

Year:

2015

Language:

english

File:

PDF, 1.85 MB

english, 2015

37

Mono-Oxidation of Bidentate Bis-Phosphines in Catalyst Activation: Kinetic and Mechanistic Studies of a Pd/Xantphos-Catalyzed C-H Functionalization

Ji, Yining, Plata, Erik, Regens, Christopher S., Hay, Michael, Schmidt, Michael, Razler, Thomas M., Qiu, Yuping, Geng, Peng, Hsiao, Yi, Rosner, Thorsten, Eastgate, Martin D., Blackmond, Donna G

Journal:

Journal of the American Chemical Society

Year:

2015

Language:

english

File:

PDF, 2.31 MB

english, 2015

38

Sulfur Mediated Ritter Reactions: The Synthesis of Cyclic Amides

Eastgate, Martin D., Fox, David J., Morley, Thomas J., Warren, Stuart

Journal:

Year:

2002

Language:

english

File:

PDF, 88 KB

english, 2002

39

Practical Ni-Catalyzed Aryl-Alkyl Cross-Coupling of Secondary Redox-Active Esters

Cornella, Josep, Edwards, Jacob T., Qin, Tian, Kawamura, Shuhei, Wang, Jie, Pan, Chung-Mao, Gianatassio, Ryan, Schmidt, Michael A., Eastgate, Martin D., Baran, Phil S.

Journal:

Journal of the American Chemical Society

Year:

2016

Language:

english

File:

PDF, 19.68 MB

english, 2016

40

Synergistic Catalysis: Pd(II) Catalyzed Oxidation of 1,4-Dihydroquinones in the Pd(II) Catalyzed 1,4-Oxidation of Cyclic-1,3-Dienes

Zheng, Bin, Schmidt, Michael A., Eastgate, Martin D.

Journal:

Journal of Organic Chemistry

Year:

2016

Language:

english

File:

PDF, 412 KB

english, 2016

41

Ligand-Promoted ortho -CH Amination with Pd Catalysts

Zhu, Dajian, Yang, Guoqiang, He, Jian, Chu, Ling, Chen, Gang, Gong, Wei, Chen, Ke, Eastgate, Martin D., Yu, Jin-Quan

Journal:

Angewandte Chemie

Year:

2015

Language:

english

File:

PDF, 530 KB

english, 2015

42

ChemInform Abstract: Palau′chlor: A Practical and Reactive Chlorinating Reagent.

Rodriguez, Rodrigo A., Pan, Chung-Mao, Yabe, Yuki, Kawamata, Yu, Eastgate, Martin D., Baran, Phil S.

Journal:

Year:

2014

File:

PDF, 22 KB

2014

43

The Impact of Palladium(II) Reduction Pathways on the Structure and Activity of Palladium(0) Catalysts

Wei, Carolyn S., Davies, Geraint H. M., Soltani, Omid, Albrecht, Jacob, Gao, Qi, Pathirana, Charles, Hsiao, Yi, Tummala, Srinivas, Eastgate, Martin D.

Journal:

Angewandte Chemie

Year:

2013

Language:

english

File:

PDF, 520 KB

english, 2013

44

ChemInform Abstract: Natural Product Synthesis in the Age of Scalability

Kuttruff, Christian A., Eastgate, Martin D., Baran, Phil S.

Journal:

Year:

2014

File:

PDF, 12 KB

2014

45

ChemInform Abstract: Ligand-Promoted ortho-C-H Amination with Pd Catalysts.

Zhu, Dajian, Yang, Guoqiang, He, Jian, Chu, Ling, Chen, Gang, Gong, Wei, Chen, Ke, Eastgate, Martin D., Yu, Jin-Quan

Journal:

Year:

2015

File:

PDF, 23 KB

2015

46

ChemInform Abstract: Synthesis of the 6-Azaindole Containing HIV-1 Attachment Inhibitor Pro-Drug, BMS-663068.

Eastgate, Martin D., et al., et al.

Journal:

Year:

2015

File:

PDF, 14 KB

2015

47

Stereoselective bulk synthesis of CCR2 antagonist BMS-741672: Assembly of an all-cis ( S,R,R )-1,2,4-triamino-cyclohexane (TACH) core via sequential heterogeneous asymmetric hydrogenations.

Deerberg, Joerg, Prasad, Siva J., Sfouggatakis, Chris, Eastgate, Martin D., Fan, Yu, Chidambaram, Ramakrishnan, Sharma, Praveen Kumar, Li, Li, Schild, Richard L., Muslehiddinoglu, Jale, Chung, Hyei-Jh

Journal:

Organic Process Research & Development

Year:

2016

Language:

english

File:

PDF, 1.29 MB

english, 2016

48

Pd-catalyzed γ-C(sp 3 )–H Arylation of Free Amines Using a Transient Directing Group

Wu, Yongwei, Chen, Yan-Qiao, Liu, Tao, Eastgate, Martin, Yu, Jin-Quan

Journal:

Journal of the American Chemical Society

Year:

2016

Language:

english

File:

PDF, 997 KB

english, 2016

49

A Data-Driven Strategy for Predicting Greenness Scores, Rationally Comparing Synthetic Routes and Benchmarking PMI Outcomes for the Synthesis of Molecules in the Pharmaceutical Industry

Li, Jun, Simmons, Eric, Eastgate, Martin David

Journal:

Green Chemistry

Year:

2016

Language:

english

File:

PDF, 2.64 MB

english, 2016

50

Nickel-Catalyzed Barton Decarboxylation and Giese Reactions: A Practical Take on Classic Transforms

Qin, Tian, Malins, Lara R., Edwards, Jacob T., Merchant, Rohan R., Novak, Alexander J. E., Zhong, Jacob Z., Mills, Riley B., Yan, Ming, Yuan, Changxia, Eastgate, Martin D., Baran, Phil S.

Journal:

Angewandte Chemie

Year:

2017

Language:

english

File:

PDF, 2.49 MB

english, 2017